油气藏评价与开发 >
2025 , Vol. 15 >Issue 4: 632 - 640
DOI: https://doi.org/10.13809/j.cnki.cn32-1825/te.2025.04.012
地质封存过程中CO2注入对地层影响研究进展
收稿日期: 2024-06-25
网络出版日期: 2025-07-19
基金资助
中国石油科技专项“咸水层二氧化碳封存协同烟气处置方法研究”(2023ZZ1301);内蒙古自治区科技重大专项“化工产业CO2减排及其高值化利用的新材料、新机制、新途径”(2021ZD0020);中国石油大学(北京)校基金项目“CCUS地质封存中固井水泥智能响应封窜体系协同调控机制研究”(ZX20200133);国家自然科学基金项目“CCUS地质封存中CO2-咸水-地层岩-油井水泥相互作用机理的研究”(51604288)
Research progress on effects of CO2 injection on formations during geological storage
Received date: 2024-06-25
Online published: 2025-07-19
CO2地质封存作为碳捕集、利用与封存(CCUS)技术中的重要一环,决定了CCUS技术的发展潜力和发展方向,是实现“双碳”目标的有效手段,明确CO2注入产生的一系列地层响应对于安全高效注入具有重要意义。压力提升是限制封存容量和封存安全的主要因素,流体溶解运移沉淀是影响地层稳定性和封存效率的本质特征,储层可注性及盖层安全性是决定地质封存项目成败的关键。系统讨论了CO2注入引起的压力聚集、压力传导、CO2-水-岩相互作用、矿物溶解沉淀及岩石孔隙结构特征等方面的地层响应特征,总结了润湿性、孔隙度、渗透率、流体性质、岩石强度、盖层完整性、地表形变及断层活化对储层可注性和盖层安全性的影响,指出目前研究存在的压力变化规律难预测、反应机理不明晰、注入效率不高效、监测评估尚不完善等主要问题。未来需要深化对封存机理的理解,改善地层响应的监测和评估方法,加强环境风险评估,进一步推动CO2地质封存技术的安全、高效应用,为应对全球气候变化问题提供有力支持。
王展鹏 , 刘双星 , 刘琦 , 杨术刚 , 张敏 , 鲜成钢 , 翁艺斌 . 地质封存过程中CO2注入对地层影响研究进展[J]. 油气藏评价与开发, 2025 , 15(4) : 632 -640 . DOI: 10.13809/j.cnki.cn32-1825/te.2025.04.012
As a critical component of Carbon Capture, Utilization and Storage (CCUS) technology, CO2 geological storage plays a decisive role in the development potential and direction of CCUS technology, and serves as an effective means to achieve “dual carbon” goals. Clarifying the series of formation responses caused by CO2 injection is essential for safe and efficient injection. Pressure buildup is a primary factor constraining the storage capacity and safety. Fluid dissolution, migration, and precipitation are the fundamental features affecting formation stability and storage efficiency. In addition, reservoir injectivity and caprock integrity are key determinants for the success of geological storage projects. The formation response characteristics caused by CO2 injection were systematically discussed, including pressure buildup, pressure propagation, CO2-water-rock interactions, mineral dissolution and precipitation, and rock pore structure characteristics. The influences of wettability, porosity, permeability, fluid properties, rock strength, caprock integrity, surface deformation, and fault activation on reservoir injectivity and caprock safety were summarized. Major current issues in research were identified, including the unpredictability of pressure change patterns, unclear reaction mechanisms, low injection efficiency, and incomplete monitoring and evaluation frameworks. Future work should deepen the understanding of storage mechanisms, improve monitoring and assessment methods of formation response, strengthen environmental risk evaluation, and further promote the safe and efficient application of CO2 geological storage technology, thereby providing strong support for addressing global climate change.
| [1] | 张贤, 杨晓亮, 鲁玺, 等. 中国二氧化碳捕集利用与封存(CCUS)年度报告(2023)[R]. 北京: 中国21世纪议程管理中心, 全球碳捕集与封存研究院, 清华大学, 2023. |
| ZHANG Xian, YANG Xiaoliang, LU Xi, et al. China Carbon Dioxide Capture, Utilization and Storage (CCUS) Annual Report (2023)[R]. Beijing: China Agenda 21 Management Center, Global Carbon Capture and Storage Research Institute, Tsinghua University, 2023. | |
| [2] | REZK M G, IBRAHIM A F, ADEBAYO A R. Uncertainty quantification for CO2 storage during intermittent CO2-EOR in oil reservoirs[J]. International Journal of Coal Geology, 2023, 266: 104177. |
| [3] | 周银邦, 王锐, 何应付, 等. 咸水层CO2地质封存典型案例分析及对比[J]. 油气地质与采收率, 2023, 30(2): 162-167. |
| ZHOU Yinbang, WANG Rui, HE Yingfu, et al. Analysis and comparison of typical cases of CO2 geological storage in saline aquifer[J]. Petroleum Geology and Recovery Efficiency, 2023, 30(2): 162-167. | |
| [4] | 柯怡兵, 李义连, 张炜, 等. 岩盐沉淀对咸水层二氧化碳地质封存注入过程的影响: 以江汉盆地为例[J]. 地质科技情报, 2012, 31(3): 109-115. |
| KE Yibing, LI Yilian, ZHANG Wei, et al. Impact of halite precipitation on CO2 injection into saline aquifers: A case study of Jianghan basin[J]. Geological Science and Technology Information, 2012, 31(3): 109-115. | |
| [5] | 胡叶军, 王蔚, 任杰, 等. 深部咸水层CO2地质封存对地层压力环境的影响[J]. 河海大学学报(自然科学版), 2016, 44(6): 512-518. |
| HU Yejun, WANG Wei, REN Jie, et al. Effect of CO2 geological sequestration in deep saline aquifer on formation pressure environment[J]. Journal of Hohai University (Natural Sciences), 2016, 44(6): 512-518. | |
| [6] | 王永胜. CO2咸水层封存砂岩储层孔隙尺度变化规律及可注性研究: 基于神华CCS示范工程[D]. 武汉: 中国地质大学, 2021. |
| WANG Yongsheng. Study on the variation of pore scale and injectability of CO2 saltwater sequestered sandstone reservoir[D]. Wuhan: China University of Geosciences, 2021. | |
| [7] | KIM K Y, HAN W S, OH J, et al. Characteristics of salt-precipitation and the associated pressure build-up during CO2 storage in saline aquifers[J]. Transport in Porous Media, 2012, 92(2): 397-418. |
| [8] | 汤翔. 致密油藏衰竭开采压力传导规律与吞吐开发动态研究[D]. 北京: 中国石油大学(北京), 2022. |
| TANG Xiang. Study on the pressure conduction law of depletion and dynamic characteristics of huff and puff in tight oil reservoir[D]. Beijing: China University of Petroleum (Beijing), 2022. | |
| [9] | BERGMO P E S, GRIMSTAD A A, LINDEBERG E. Simultaneous CO2 injection and water production to optimise aquifer storage capacity[J]. International Journal of Greenhouse Gas Control, 2011, 5(3): 555-564. |
| [10] | 王千, 申建, 赵岳, 等. 煤系致密砂岩储层注CO2启动压力梯度动态规律[J]. 煤炭学报, 2023, 48(8): 3172-3181. |
| WANG Qian, SHEN Jian, ZHAO Yue, et al. Dynamic threshold pressure gradient characteristics of CO2 injection in coal-measure tight sandstone reservoirs[J]. Journal of China Coal Society, 2023, 48(8): 3172-3181. | |
| [11] | 赵宁宁. 二氧化碳地质储存中储层孔渗及矿物特征对其运移演化的影响[D]. 长春: 吉林大学, 2018. |
| ZHAO Ningning. Study on the influence of porosity and permeability and mineral characteristics on CO2 geological storage[D]. Changchun: Jilin University, 2018. | |
| [12] | 高阳. 鄂尔多斯盆地CCS地质封存中CO2-咸水-地层岩反应研究[D]. 北京: 中国石油大学(北京), 2018. |
| GAO Yang. Investigation of CO2-formation brine-rock reaction of Shenhua Ordos CCS project[D]. Beijing: China University of Petroleum (Beijing), 2018. | |
| [13] | 张烈辉, 张涛, 赵玉龙, 等. 二氧化碳-水-岩作用机理及微观模拟方法研究进展[J]. 石油勘探与开发, 2024, 51(1): 199-211. |
| ZHANG Liehui, ZHANG Tao, ZHAO Yulong, et al. A review of interaction mechanisms and microscopic simulation methods for CO2-water-rock system[J]. Petroleum Exploration and Development, 2024, 51(1): 199-211. | |
| [14] | 施雷庭, 户海胜, 张玉龙, 等. 致密砂砾岩矿物与超临界CO2和地层水相互作用[J]. 油田化学, 2019, 36(4): 640-645. |
| SHI Leiting, HU Haisheng, ZHANG Yulong, et al. Interaction of tight glutenite mineral with supercritical CO2 and formation water[J]. Oilfield Chemistry, 2019, 36(4): 640-645. | |
| [15] | 王闯. 砂岩超临界CO2渗流特征及水岩作用影响研究[D]. 徐州: 中国矿业大学, 2019. |
| WANG Chuang. Seepage characteristics of supercritical CO2 in sandstone and influence of water-rock interaction[D]. Xuzhou: China University of Mining and Technology, 2019. | |
| [16] | 李富杰, 齐有强, 弓昊天. 矿物溶解再沉淀过程研究综述[J]. 矿物岩石地球化学通报, 2024, 43(1): 240-258. |
| LI Fujie, QI Youqiang, GONG Haotian. Review on the process of mineral dissolution and reprecipitation[J]. Bulletin of Mineralogy, Petrology and Geochemistry, 2024, 43(1): 240-258. | |
| [17] | 沈臻欢, 于炳松, 韩舒筠, 等. 碳酸盐胶结物溶解—沉淀的热力学平衡在碎屑岩储层质量预测中的应用: 以渤南洼陷沙三段为例[J]. 东北石油大学学报, 2018, 42(5): 63-72, 9. |
| SHEN Zhenhuan, YU Bingsong, HAN Shujun, et al. Application of thermodynamic equilibrium for dissolution-precipitation of carbonate cements in prediction of clastic reservoir quality: A case study from Es3, Bonan sag[J]. Journal of Northeast Petroleum University, 2018, 42(5): 63-72, 9. | |
| [18] | MULLER N, QI R, MACKIE E, et al. CO2 injection impairment due to halite precipitation[J]. Energy Procedia, 2009, 1(1): 3507-3514. |
| [19] | SPYCHER N, PRUESS K, ENNIS-KING J. CO2-H2O mixtures in the geological sequestration of CO2. I. Assessment and calculation of mutual solubilities from 12 to 100 ℃ and up to 600 bar[J]. Geochimica et Cosmochimica Acta, 2003, 67(16): 3015-3031. |
| [20] | KIM M, SELL A, SINTON D. Aquifer-on-a-chip: Understanding pore-scale salt precipitation dynamics during CO2 sequestration[J]. Lab on a Chip, 2013, 13(13): 2508-2518. |
| [21] | 刘漪雯, 付美龙, 王长权, 等. 二氧化碳驱后微粒运移对低渗透储层的伤害及对渗流能力的影响[J]. 油田化学, 2024, 41(2): 238-244. |
| LIU Yiwen, FU Meilong, WANG Changquan, et al. Damage of particle migration to low permeability reservoir after carbon dioxide flooding and its influence on seepage capacity[J]. Oilfield Chemistry, 2024, 41(2): 238-244. | |
| [22] | 杨术刚, 蔡明玉, 张坤峰, 等. CO2-水-岩相互作用对CO2地质封存体物性影响研究进展及展望[J]. 油气地质与采收率, 2023, 30(6): 80-91. |
| YANG Shugang, CAI Mingyu, ZHANG Kunfeng, et al. Research progress and prospect of CO2-water-rock interaction on petrophysical properties of CO2 geological sequestration[J]. Petroleum Geology and Recovery Efficiency, 2023, 30(6): 80-91. | |
| [23] | LIU Q, LI J, LIANG B, et al. Microscopic flow of CO2 in complex pore structures: A recent 10-year review[J]. Sustainability, 2023, 15(17): 12959. |
| [24] | 杨国栋. 鄂尔多斯盆地二氧化碳地质封存机理研究[D]. 武汉: 中国地质大学, 2015. |
| YANG Guodong. Study on the mechanism of carbon dioxide geological storage in Ordos Basin[D]. Wuhan: China University of Geosciences, 2015. | |
| [25] | 李颖, 马寒松, 李海涛, 等. 超临界CO2对碳酸盐岩储层的溶蚀作用研究[J]. 油气藏评价与开发, 2023, 13(3): 288-295. |
| LI Ying, MA Hansong, LI Haitao, et al. Dissolution of supercritical CO2 on carbonate reservoirs[J]. Petroleum Reservoir Evaluation and Development, 2023, 13(3): 288-295. | |
| [26] | XIE J, ZHANG K, LI C, et al. Preliminary study on the CO2 injectivity and storage capacity of low-permeability saline aquifers at Chenjiacun site in the Ordos Basin[J]. International Journal of Greenhouse Gas Control, 2016, 52: 215-230. |
| [27] | TENG Y, WANG P, XIE H, et al. Capillary trapping characteristics of CO2 sequestration in fractured carbonate rock and sandstone using MRI[J]. Journal of Natural Gas Science and Engineering, 2022, 108: 104809. |
| [28] | DING N, SI L, WEI J, et al. Study on coal wettability under different gas environments based on the adsorption energy[J]. ACS Omega, 2023, 8(24): 22211-22222. |
| [29] | ARIF M, ABU-KHAMSIN S A, IGLAUER S. Wettability of rock/CO2/brine and rock/oil/CO2-enriched-brine systems: Critical parametric analysis and future outlook[J]. Advances in Colloid and Interface Science, 2019, 268: 91-113. |
| [30] | 肖娜, 李实, 林梅钦, 等. CO2-水-岩石相互作用对砂岩储集层润湿性影响机理[J]. 新疆石油地质, 2017, 38(4): 460-465. |
| XIAO Na, LI Shi, LIN Meiqin, et al. Influence of CO2-water-rock interactions on wettability of sandstone reservoirs[J]. Xinjiang Petroleum Geology, 2017, 38(4): 460-465. | |
| [31] | 李博文, 孙灵辉, 刘先贵, 等. CO2-水-岩地化反应对致密砂砾岩物性、可动用性和微观孔隙结构影响[J]. 应用化工, 2023, 52(6): 1615-1618, 1625. |
| LI Bowen, SUN Linghui, LIU Xiangui, et al. Effect of CO2-brine-rock reaction on physical properties, mobility and microscopic pore structure of tight conglomerate[J]. Applied Chemical Industry, 2023, 52(6): 1615-1618. | |
| [32] | 杨术刚, 张坤峰, 刘双星, 等. 页岩渗透率测定方法及影响因素研究进展[J]. 油气地质与采收率, 2023, 30(5): 31-40. |
| YANG Shugang, ZHANG Kunfeng, LIU Shuangxing, et al. Research progress on measurement methods and influencing factors of shale permeability[J]. Petroleum Geology and Recovery Efficiency, 2023, 30(5): 31-40. | |
| [33] | SONG J, ZHANG D. Comprehensive review of caprock-sealing mechanisms for geologic carbon sequestration[J]. Environmental Science & Technology, 2013, 47(1): 9-22. |
| [34] | 王紫剑, 唐玄, 荆铁亚, 等. 中国年封存量百万吨级CO2地质封存选址策略[J]. 现代地质, 2022, 36(5): 1414-1431. |
| WANG Zijian, TANG Xuan, JING Tieya, et al. Site selection strategy for an annual million-ton scale CO2 geological storage in China[J]. Geoscience, 2022, 36(5): 1414-1431. | |
| [35] | 陈博文, 王锐, 李琦, 等. CO2地质封存盖层密闭性研究现状与进展[J]. 高校地质学报, 2023, 29(1): 85-99. |
| CHEN Bowen, WANG Rui, LI Qi, et al. Status and advances of research on caprock sealing properties of CO2 geological storage[J]. Geological Journal of China Universities, 2023, 29(1): 85-99. | |
| [36] | 陈晨, 何邢益, 牛庆合, 等. 超临界CO2注入煤层对顶板岩石纵波速度及力学响应特征研究[J]. 煤田地质与勘探, 2021, 49(5): 98-104. |
| CHEN Chen, HE Xingyi, NIU Qinghe, et al. Study on P-wave velocity and mechanical response characteristic of rock in coal seam roof with supercritical CO2 injection[J]. Coal Geology & Exploration, 2021, 49(5): 98-104. | |
| [37] | 侯冰, 宋振云, 贾建鹏, 等. 超临界二氧化碳对致密砂岩力学特性影响的实验研究 [J]. 中国海上油气, 2018, 30(5): 109-115. |
| HOU Bing, SONG Zhenyun, JIA Jianpeng, et al. Experimental study on the effect of supercritical carbon dioxide on mechanical properties of tight sandstone [J]. China Offshore Oil and Gas, 2018, 30(5): 109-115. | |
| [38] | 于子望, 卢帅屹, 白林, 等. CO2地质封存岩石力学问题研究进展[J]. 吉林大学学报(地球科学版), 2023, 53: 1-15. |
| YU Ziwang, LU Shuaiyi, BAI Lin, et al. Research progress on rock mechanics of CO2 geological sequestration[J]. Journal of Jilin University (Earth Science Edition), 2023, 53: 1-15. | |
| [39] | 刘思雨, 杨国栋, 黄冕, 等. 人工裂缝参数对CO2-ESGR中CO2封存和CH4开采的影响[J]. 石油与天然气化工, 2024, 53(2): 94-100. |
| LIU Siyu, YANG Guodong, HUANG Mian, et al. Effects of artificial fracture parameters on CO2 sequestration and CH4 production in CO2-ESGR[J]. Chemical Engineering of Oil & Gas, 2024, 53(2): 94-100. | |
| [40] | WANG S, HUANG Z, WU Y S, et al. A semi-analytical correlation of thermal-hydraulic-mechanical behavior of fractures and its application to modeling reservoir scale cold water injection problems in enhanced geothermal reservoirs[J]. Geothermics, 2016, 64: 81-95. |
| [41] | 李会元. 废弃油气藏CO2埋存过程中盖层完整性的评价[D]. 大庆: 东北石油大学, 2015. |
| LI Huiyuan. Evaluation for the caprock integrity of the CO2 sequestration in depleted oil and gas reservoirs[D]. Daqing: Northeast Petroleum University, 2015. | |
| [42] | 崔振东, 刘大安, 曾荣树, 等. CO2地质封存工程的潜在地质环境灾害风险及防范措施[J]. 地质论评, 2011, 57(5): 700-706. |
| CUI Zhendong, LIU Daan, ZENG Rongshu, et al. Potential geological and environmental risks and its prevention measures for CO2 geological storage projects[J]. Geological Review, 2011, 57(5): 700-706. | |
| [43] | STREIT J E, HILLIS R R. Estimating fault stability and sustainable fluid pressures for underground storage of CO2 in porous rock[J]. Energy, 2004, 29(9/10): 1445-1456. |
| [44] | TAGHIPOUR M, GHAFOORI M, LASHKARIPOUR G R, et al. A geomechanical evaluation of fault reactivation using analytical methods and numerical simulation[J]. Rock Mechanics and Rock Engineering, 2021, 54(2): 695-719. |
| [45] | 王展鹏, 刘琦, 叶航, 等. CO2地质封存泄漏监测技术研究进展[J]. 环境工程, 2023, 41(10): 69-81. |
| WANG Zhanpeng, LIU Qi, YE Hang, et al. Research progress on CO2 geological storage leakage and monitoring[J]. Environmental Engineering, 2023, 41(10): 69-81. |
/
| 〈 |
|
〉 |