淀粉接枝共聚物凝胶堵水效果及作用机理研究

摘要/Abstract

摘要：

渤海油田具有储层岩心胶结疏松、非均质性严重、原油黏度较高、平均渗透率较高和单井注水量较大等特点,注水开发不仅极易发生突进,而且注水开发对岩石结构冲刷和破坏作用会进一步加剧储层非均质性。为满足高含水期稠油油藏堵水技术需求,以物理化学、高分子材料学和油藏工程等为理论指导,以化学分析、仪器检测和物理模拟等为实验手段,以渤海SZ36—1油田储层岩石和流体为研究对象,开展了淀粉接枝共聚物凝胶堵水效果及作用机理研究。结果表明,当堵水剂组成为“4 %淀粉+4 %丙烯酰胺+0.036 %交联剂+0.012 %引发剂+0.002 %无水亚硫酸钠”时,堵水剂合理段塞尺寸在0.025 PV~0.075 PV。对于“边水+直井”模型,随原油黏度增加,水驱采收率降低。油井堵水后,含水率降低,但产液速度降低。原油黏度愈高,含水率降幅愈大,采收率增幅愈大,但最终采收率仍然较低。与“单边水+直井”模型相比较,“多边水+直井”模型水驱采收率较高,堵水增油降水效果更好。对于处于中高含水开发期油藏,由于前期水驱、调剖和化学驱等措施的影响,水井井壁附近区域剩余油饱和度较低,而油井井壁附近中低渗透层剩余油饱和度较高。因此,堵水措施增油降水效果要明显好于调剖措施的效果。

关键词: 海上稠油油藏, 堵水效果, 参数优化, 物理模拟, 机理探讨

Abstract:

Bohai oilfield has the characteristics of loose cementation, serious heterogeneity, high viscosity of crude oil, high average permeability and large amount of water injection in a single well. The breakthrough phenomenon of water injection development was serious, and the injection water erosion also caused damage to rock structure. Then we formed inefficient and ineffective circulation between injection and production wells, seriously affecting the effect of water flooding development, and bringing great risks to subsequent chemical flooding development. In order to satisty the heavy oil reservoir of high water shutoff technology needs, based on the physical chemistry, polymer materials and reservoir engineering theory, and taking the chemical analysis, detection equipment and physical simulation as an experimental method, we took the reservoir rock and fluid in SZ-361 field of Bohai oilfield as the research object to study the water plugging effect and mechanism of starch graft copolymer gel. The results showed that when the water plugging agent group was "starch（4 %）+ acrylamide（4 %） + crosslinking agent（0.036 %） + initiator（0.012 %） +anhydrous sodium sulfite（0.002 %）", the reasonable slug size of water plugging agent was between 0.025PV and 0.075PV. For the model of "edge water and vertical oil well", the oil recovery of water flooding decreases with the increase of crude oil viscosity. After water plugging in the oil well, the liquid production rate decreases when the water content drops. The higher the viscosity of crude oil is, the greater the decline of water content and the recovery rate will be, but the ultimate recovery is still lower. Compared with the model of "single water and vertical oil well", the model of "multilateral water and vertical oil well" had higher water flooding recovery, and the effect of water plugging and oil increasing was better. For the high water cut development period of reservoir, due to the impact of early water flooding and chemical flooding profile control and other measures, the remaining oil saturation near the water wells borehole area was low, but the residual oil saturation in low permeability reservoirs near the wellbore was higher. Therefore, the effect of water plugging measures on increasing oil and precipitation was much better than that of profile control measures.

Key words: offshore heavy oil reservoir, water plugging effect, parameter optimization, physical simulation, mechanism study

中图分类号:

TE39

曹伟佳,卢祥国,张云宝,徐国瑞,李翔. 淀粉接枝共聚物凝胶堵水效果及作用机理研究[J]. 油气藏评价与开发, 2019, 9(1): 44-50.

Cao Weijia,Lu Xiangguo,Zhang Yunbao,Xu Guorui,Li Xiang. Study on water plugging effect and mechanism of starch graft copolymer gel[J]. Reservoir Evaluation and Development, 2019, 9(1): 44-50.

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参考文献 21

[1]	熊春明, 唐孝芬 . 国内外堵水调剖技术最新进展及发展趋势[Jl. 石油勘探与开发, 2007,34(1):83-88. doi: 10.3321/j.issn:1000-0747.2007.01.016
[2]	韩大匡 . 中国油气田开发现状、面临的挑战和技术发展方向[J]. 中国工程科学, 2010,12(5):51-57. doi: 10.3969/j.issn.1009-1742.2010.05.008
[3]	郝乐伟, 王琪, 唐俊 . 储层岩石微观孔隙结构研究方法与理论综述[J]. 岩性油气藏, 2013,25(5):123-128. doi: 10.3969/j.issn.1673-8926.2013.05.023
[4]	宋欢, 张脊, 卢祥国 , 等. 低渗透油藏液流转向剂传输运移能力与驱油效率[J]. 大庆石油地质与开发, 2017,36(4):116-122. doi: 10.19597/J.ISSN.1000-3754.201612090
[5]	陈建波, 刘东 . 海上稠油油田热采吞吐后转驱采收率研究[J]. 油气藏评价与开发, 2015,5(4):46-49. doi: 10.3969/j.issn.2095-1426.2015.04.010
[6]	田中敬, 赵隆顺, 高广亮 , 等. 复杂断块底水油藏含水上升规律[J]. 大庆石油地质与开发, 2017,36(3):56-59. doi: 10.3969/J.ISSN.1000-3754.2017.03.010
[7]	陈程, 宋新民, 李军 . 曲流河点砂坝储层水流优势通道及其对剩余油分布的控制[J]. 石油学报, 2012,33(2):257-263. doi: 10.7623/syxb201202010
[8]	黄颖辉, 刘东, 李金蔓 , 等. 弱凝胶矿场调驱效果评价方法研究[J]. 油气藏评价与开发, 2013,3(2):62-65. doi: 10.3969/j.issn.2095-1426.2013.02.013
[9]	王增林, 张民, 杨勇 , 等. 稠油热化学驱过程中影响因素及其交互作用对采收率的影响[J]. 油气地质与采收率, 2017,24(1):64-68.
[10]	卢祥国, 高振环, 闫文华 , 等. 人造岩心渗透率影响因素试验研究[J]. 大庆石油地质与开发, 1994,13(4):53-55.
[11]	卢祥国, 宋合龙, 王景盛 , 等. 石英砂环氧树脂胶结非均质模型制作方法:中国,ZL200510063665.8[P]. 2005-09.
[12]	王婷婷, 曹伟佳, 卢祥国 . 半互穿网络结构凝胶粘度及其影响因素[J]. 石油化工高等学校学报, 2016,29(5):70-76. doi: 10.3969/j.issn.1006-396X.2016.05.012
[13]	刘玉明, 孙雷, 杨凯雷 , 等. WZ11—7海上低渗油田保压开采驱替方式实验评价研究[J]. 油气藏评价与开发, 2014,4(5):34-39. doi: 10.3969/j.issn.2095-1426.2014.05.007
[14]	赵福麟, 王业飞, 戴彩丽 , 等. 聚合物驱后提高采收率技术研究[J]. 中国石油大学学报(自然科学版), 2006,30(1):86-89. doi: 10.3321/j.issn:1000-5870.2006.01.018
[15]	赵福麟, 戴彩丽, 王业飞 . 海上油田提高采收率的控水技术[J]. 中国石油大学学报(自然科学版), 2006,30(2):53-58. doi: 10.3321/j.issn:1000-5870.2006.02.012
[16]	卢祥国, 胡广斌, 曹伟佳 , 等. 聚合物滞留特性对化学驱提高采收率的影响[J]. 大庆石油地质与开发, 2016,35(3):99-105. doi: 10.3969/J.ISSN.1000-3754.2016.03.019
[17]	Wang D M, Wang G, Wu W X, et al. The influence of viscoelasticity on displacement efficiency from micro to macro scale[C]// paper SPE-109016-MS presented at the SPE Annual Technical Conference and Exhibition, 11-14 November 2007, Anaheim, California, USA.
[18]	Xie K, Lu X G, Li Q , et al. Analysis of reservoir applicability of hydrophobically associating polymer[J]. SPE Journal, 2016,21(1):1-9. doi: 10.2118/174553-PA
[19]	韩培慧, 赵群, 穆爽书 , 等. 聚合物驱后进一步提高采收率途径的研究[J]. 大庆石油地质与开发, 2006,25(5):81-84. doi: 10.3969/j.issn.1000-3754.2006.05.023
[20]	李宜强, 隋新光, 李洁 , 等. 纵向非均质大型平面模型聚合物驱油波及系数室内实验研究[J]. 石油学报, 2005,26(2):77-84. doi: 10.3321/j.issn:0253-2697.2005.02.017
[21]	兰玉波, 杨清彦, 李斌会 , 等. 聚合物驱波及系和驱油效率实验研究[J]. 石油学报, 2006,27(1):65-68. doi: 10.3321/j.issn:0253-2697.2006.01.013

离子组成							总矿化度
Na⁺+K⁺	Mg²⁺	Ca²⁺	Cl^-	SO₄^2-	HCO₃^-	CO₃^2-	总矿化度
3 093.2	305.5	275.6	5 879.7	85.3	311.5	0	9 947.8

方案编号	堵水剂段塞尺寸/PV	含油饱和度,%	采收率,%
方案编号	堵水剂段塞尺寸/PV	含油饱和度,%	水驱	最终	增幅
1—1	0.025	72.6	37.2	52.7	15.5
1—2	0.050	71.9	37.4	54.7	17.3
1—3	0.075	71.7	37.0	57.5	20.5
1—4	0.100	71.4	36.8	59.1	22.3
1—5	0.125	71.8	36.4	59.8	23.4

方案编号	原油黏度/ （mPa·s）	含油饱和度, %	采收率,%
方案编号	原油黏度/ （mPa·s）	含油饱和度, %	水驱	最终	增幅
2—1	15	71.9	39.6	60.9	21.3
2—2	45	71.7	37.0	57.5	20.5
2—3	75	72.0	34.8	54.2	19.4
2—4	150	72.5	30.8	49.0	18.2

方案编号	原油黏度/ （mPa·s）	含油饱和度, %	采收率,%
方案编号	原油黏度/ （mPa·s）	含油饱和度, %	水驱	最终	增幅
3—1	15	74.2	41.3	47.0	5.7
3—2	45	74.3	38.1	46.4	8.3
3—3	75	74.2	34.4	44.6	10.2
3—4	150	73.9	30.6	43.3	12.7

方案编号	原油黏度/ （mPa·s）	含油饱和度, %	采收率,%
方案编号	原油黏度/ （mPa·s）	含油饱和度, %	水驱	最终	增幅
4—1	15	70.7	43.8	51.7	7.9
4—2	45	70.1	41.5	51.0	9.5
4—3	75	69.9	39.1	50.6	11.5
4—4	150	70.4	36.2	49.0	12.8