Petroleum Reservoir Evaluation and Development ›› 2024, Vol. 14 ›› Issue (3): 343-351.doi: 10.13809/j.cnki.cn32-1825/te.2024.03.004
• Methodology and Theory • Previous Articles Next Articles
TANG Yong1(),CHEN Kun1,HU Xiaohu2,3,FANG Sidong2,3,LIU Hua2,3
Received:
2023-07-17
Online:
2024-07-10
Published:
2024-06-26
CLC Number:
Yong TANG,Kun CHEN,Xiaohu HU, et al. Phase behavior and development characteristics of shale condensate gas in confined space[J]. Petroleum Reservoir Evaluation and Development, 2024, 14(3): 343-351.
Table 1
Results of a single flash distillation experiment %"
组分 | 闪蒸气 摩尔分数 | 闪蒸油 摩尔分数 | 井流物 摩尔分数 | 井流物 质量分数 |
---|---|---|---|---|
CO2 | 0.198 8 | 0 | 0.185 6 | 0.283 0 |
N2 | 0.424 7 | 0 | 0.396 6 | 0.384 8 |
C1 | 81.870 9 | 0 | 76.436 9 | 42.473 5 |
C2 | 10.468 5 | 0.299 0 | 9.793 6 | 10.202 0 |
C3 | 3.855 6 | 0.334 5 | 3.621 9 | 5.533 4 |
iC4 | 0.806 1 | 0.218 2 | 0.767 1 | 1.544 5 |
nC4 | 1.132 4 | 0.541 2 | 1.093 1 | 2.200 9 |
iC5 | 0.606 6 | 1.119 4 | 0.640 6 | 1.601 2 |
nC5 | 0.428 8 | 1.143 4 | 0.476 2 | 1.190 2 |
C6 | 0.207 6 | 5.586 2 | 0.564 6 | 1.682 0 |
C7 | 0 | 10.915 3 | 0.724 5 | 2.409 4 |
C8 | 0 | 16.185 7 | 1.074 3 | 3.982 1 |
C9 | 0 | 11.875 3 | 0.788 2 | 3.303 9 |
C10 | 0 | 9.700 6 | 0.643 8 | 2.988 8 |
C11+ | 0 | 42.081 4 | 2.793 0 | 20.220 4 |
Table 2
Critical temperature of pseudo-components under different pore radius"
孔隙半径/nm | 临界温度/K | |||||
---|---|---|---|---|---|---|
N2—C1 | CO2—C3 | iC4—nC4 | iC5—nC5 | C6—C9 | C10+ | |
非受限 | 196.98 | 50.87 | 144.89 | 191.15 | 240.45 | 446.48 |
100 | 196.25 | 322.61 | 415.89 | 461.74 | 510.56 | 713.73 |
40 | 195.14 | 320.49 | 412.67 | 457.92 | 506.04 | 704.93 |
30 | 194.53 | 319.31 | 410.89 | 455.8 | 503.53 | 700.06 |
20 | 193.31 | 316.97 | 407.34 | 451.58 | 498.54 | 690.39 |
10 | 189.68 | 310.01 | 396.78 | 439.05 | 483.73 | 661.82 |
5 | 182.52 | 296.33 | 376.13 | 414.57 | 454.84 | 606.65 |
2 | 161.97 | 257.33 | 317.82 | 345.76 | 374.05 | 457.08 |
Table 3
Critical pressure of pseudo-components under different pore radius"
孔隙半径/nm | 临界压力/MPa | |||||
---|---|---|---|---|---|---|
N2—C1 | CO2—C3 | iC4—nC4 | iC5—nC5 | C6—C9 | C10+ | |
非受限 | 4.59 | 4.73 | 3.74 | 3.38 | 3.05 | 1.59 |
100 | 4.58 | 4.71 | 3.72 | 3.36 | 3.03 | 1.58 |
40 | 4.55 | 4.68 | 3.69 | 3.33 | 3.01 | 1.55 |
30 | 4.54 | 4.66 | 3.67 | 3.32 | 2.99 | 1.55 |
20 | 4.51 | 4.63 | 3.64 | 3.29 | 2.96 | 1.53 |
10 | 4.42 | 4.53 | 3.55 | 3.20 | 2.87 | 1.46 |
5 | 4.26 | 4.33 | 3.36 | 3.02 | 2.70 | 1.34 |
2 | 3.78 | 3.76 | 2.84 | 2.52 | 2.22 | 1.01 |
[1] | 王红岩, 周尚文, 赵群, 等. 川南地区深层页岩气富集特征、勘探开发进展及展望[J]. 石油与天然气地质, 2023, 44(6): 1430-1441. |
WANG Hongyan, ZHOU Shangwen, ZHAO Qun, et al. Enrichment characteristics,exploration and exploitation progress, and prospects of deep shale gas in the southern Sichuan Basin, China[J]. Oil & Gas Geology, 2023, 44(6): 1430-1441. | |
[2] | WANG Q, CHEN X, JHA A N, et al. Natural gas from shale formation: The evolution, evidences and challenges of shale gas revolution in United States[J]. Renewable and Sustainable Energy Reviews, 2014, 30: 1-28. |
[3] | 朱维耀, 岳明, 刘昀枫, 等. 中国致密油藏开发理论研究进展[J]. 工程科学学报, 2019, 41(9): 1103-1114. |
ZHU Weiyao, YUE Ming, LIU Yunfeng, et al. Research progress on tight oil exploration in China[J]. Chinese Journal of Engineering, 2019, 41(9): 1103-1114. | |
[4] | ISMAIL M I A, HORNE R N. An Investigation of Gas-Condensate Flow in Liquid-Rich Shales[C]// Paper SPE-169021-MS presented at the SPE Unconventional Resources Conference, The Woodlands, Texas, USA, April 2014. |
[5] |
孙焕泉, 周德华, 蔡勋育, 等. 中国石化页岩气发展现状与趋势[J]. 中国石油勘探, 2020, 25(2): 14-26.
doi: 10.3969/j.issn.1672-7703.2020.02.002 |
SUN Huanquan, ZHOU Dehua, CAI Xunyu, et al. Progress and prospect of shale gas development of Sinopec[J]. China Petroleum Exploration, 2020, 25(2): 14-26.
doi: 10.3969/j.issn.1672-7703.2020.02.002 |
|
[6] | 胡德高, 舒志国, 郭战峰, 等. 川东复兴地区侏罗系(涪页10HF井)发现国内首个页岩凝析气藏[J]. 中国地质, 2021, 48(6): 1980-1981. |
HU Degao, SHU Zhiguo, GUO Zhanfeng, et al. Discovery of the first shale condensate gas reservoir in Jurassic strata in the Fuxin area, eastern Sichuan[J]. Geology in China, 2021, 48(6): 1980-1981. | |
[7] | 郭旭升, 胡东风, 魏志红, 等. 涪陵页岩气田的发现与勘探认识[J]. 中国石油勘探, 2016, 21(3): 24-37. |
GUO Xusheng, HU Dongfeng, WEI Zhihong, et al. Discovery and exploration of Fuling shale gas field[J]. China Petroleum Exploration, 2016, 21(3): 24-37. | |
[8] | 王志刚. 涪陵页岩气勘探开发重大突破与启示[J]. 石油与天然气地质, 2015, 36(1): 1-6. |
WANG Zhigang. Breakthrough of Fuling shale gas exploration and development and its inspiration[J]. Oil & Gas Geology, 2015, 36(1): 1-6. | |
[9] |
马新华, 谢军, 雍锐, 等. 四川盆地南部龙马溪组页岩气储集层地质特征及高产控制因素[J]. 石油勘探与开发, 2020, 47(5): 841-855.
doi: 10.11698/PED.2020.05.01 |
MA Xinhua, XIE Jun, YONG Rui, et al. Geological characteristics and high production control factors of shale gas reservoirs in Silurian Longmaxi Formation, southern Sichuan Basin, SW China[J]. Petroleum Exploration and Development, 2020, 47(5): 841-855.
doi: 10.11698/PED.2020.05.01 |
|
[10] |
金之钧, 胡宗全, 高波, 等. 川东南地区五峰组-龙马溪组页岩气富集与高产控制因素[J]. 地学前缘, 2016, 23(1): 1-10.
doi: 10.13745/j.esf.2016.01.001 |
JIN Zhijun, HU Zongquan, GAO Bo, et al. Controlling factors on the enrichment and high productivity of shale gas in the Wufeng-Longmaxi Formations, southeastern Sichuan Basin[J]. Earth Science Frontiers, 2016, 23(1): 1-10.
doi: 10.13745/j.esf.2016.01.001 |
|
[11] | 聂海宽, 张柏桥, 刘光祥, 等. 四川盆地五峰组-龙马溪组页岩气高产地质原因及启示——以涪陵页岩气田JY6-2HF为例[J]. 石油与天然气地质, 2020, 41(3): 463-473. |
NIE Haikuan, ZHANG Baiqiao, LIU Guangxiang, et al. Geological factors contributing to high shale gas yield in the Wufeng-Longmaxi Fms of Sichuan Basin: A case study of Well JY6-2HF in Fuling shale gas field[J]. Oil & Gas Geology, 2020, 41(3): 463-473. | |
[12] | 阎庆来, 何秋轩, 刘易非. 凝析油气在多孔介质中的相变特征[J]. 西安石油大学学报(自然科学版), 1988, 3(2): 15-22. |
YAN Qinglai, HE Qiuxuan, LIU Yifei. Phase transition characteristics of condensate oil and gas in porous media[J]. Journal of Xi'an Shiyou University(Natural Science Edition), 1988, 3(2): 15-22. | |
[13] | 朱维耀, 黄延章. 多孔介质对气-液相变过程的影响[J]. 石油勘探与开发, 1988, (1): 55-59. |
ZHU Weiyao, HUANG Yanzhang. The effect of porous media on gas-liquid phase behavior[J]. Petroleum Exploration and Development 1988, (1): 55-59. | |
[14] | 何江川, 李士伦. 凝析气藏真实露点的探讨[J]. 天然气工业, 1995, 15(4): 22-26. |
HE Jiangchuan, LI Shilun. Exploration of the true dew point of condensate gas reservoirs[J]. Natural Gas Industry, 1995, 15(4): 22-26. | |
[15] | 童敏, 李相方, 胡永乐, 等. 多孔介质对凝析气相态的影响[J]. 石油大学学报:自然科学版, 2004, 28(5): 61-64. |
TONG Ming, LI Xiangfang, HU Yongle, et al. Experimental study on influence of porous media on phase behavior of gas condensate[J]. Journal of China University of Petroleum(Edition of Natural Science), 2004, 28(5): 61-64. | |
[16] | 王志伟, 李相方, 程时清, 等. 多孔介质凝析气相变的影响因素[J]. 天然气工业, 2006, 26(1): 90-92. |
WANG Zhiwei, LI Xiangfang, CHENG Shiqing, et al. Influential factors on phase change of condensate gas in porous media[J]. Natural Gas Industry, 2006, 26(1): 90-92. | |
[17] | LONG K J, TANG Y, HE Y W, et al. Fluid phase behavior during multi-cycle injection and production of underground gas storage based on gas-condensate reservoirs with oil rim[J]. Geoenergy Science and Engineering, 2023, 226: 211769. |
[18] |
汤勇, 龙科吉, 王皆明, 等. 凝析气藏型储气库多周期注采过程中流体相态变化特征[J]. 石油勘探与开发, 2021, 48(2): 337-346.
doi: 10.11698/PED.2021.02.10 |
TANG Yong, LONG Keji, WANG Jieming, et al. Change of phase state during multi-cycle injection and production process of condensate gas reservoir based underground gas storage[J]. Petroleum Exploration and Development, 2021, 48(2): 337-346.
doi: 10.11698/PED.2021.02.10 |
|
[19] | 郭平, 孙良田. 多孔介质毛细管压力对凝析油气相态影响研究[J]. 石油勘探与开发, 1994, 21(4): 64-69. |
GUO Ping, SHUN Liangtian. Study on the effect of capillary pressure on condensate gas phase state in porous media[J]. Petroleum Exploration and Development, 1994, 21(4): 64-69. | |
[20] | 杜建芬, 李士伦, 孙雷, 等. 多孔介质毛细凝聚对凝析气藏露点的影响研究[J]. 天然气工业, 2001, 21(3): 56-59. |
DU Jianfen, LI Shilun, SUN Lei, et al. influence of the capillary agglomeration in porous media on the dew point of condensate gas reservoir[J]. Natural Gas Industry, 2001, 21(3): 56-59. | |
[21] | 杜建芬. 多孔介质中凝析油气体系相平衡规律和渗流规律研究[D]. 成都: 西南石油学院(南充), 1997. |
DU Jianfen. Study on phase equilibrium law and seepage law of condensate and gas system in porous media[D]. Chengdu: Southwest Petroleum Institute(Nanchong), 1997. | |
[22] | KAMARI A, LI L, SHENG J J. Effects of rock pore sizes on the PVT properties of oil and gas-condensates in shale and tight reservoirs[J]. Petroleum, 2018, 4(2): 148-157. |
[23] | SONG Z J, SONG Y L, GUO J, et al. Adsorption induced critical shifts of confined fluids in shale nanopores[J]. Chemical Engineering Journal, 2019, 385: 123837. |
[24] | 王奥, 李菊花, 郑斌. 多孔介质中凝析气相态特征[J]. 大庆石油地质与开发, 2021, 40(1): 61-67. |
WANG Ao, LI Juhua, ZHENG Bin. Study on the phase behaviors of the condensate gas in porous media[J]. Petroleum Geology & Oilfield Development in Daqing, 2021, 40(1): 61-67. | |
[25] | BITSANIS I, MAGDA J, TIRRELL M, et al. Molecular dynamics of flow in micropores[J]. Journal of Chemical Physics, 1987, 87(3): 1733-1750. |
[26] | VANFERLICK T, SCRIVEN L, DAVIS H. Molecular theories of confined fluids[J]. Journal of Chemical Physics, 1989, 90(4): 2422-2436. |
[27] | 王民, 余昌琦, 费俊胜, 等. 页岩油在干酪根中吸附行为的分子动力学模拟与启示[J]. 石油与天然气地质, 2023, 44(6): 1442-1452. |
WANG Min, YU Changqi, FEI Junsheng, et al. Molecular dynamics simulation of shale oil adsorption in kerogen and its implications[J]. Oil & Gas Geology, 2023, 44(6): 1442-1452. | |
[28] | NAJEEB S A, TADESSE W W T, THANH N N, et al. Nanopore Compositional Modeling in Unconventional Shale Reservoirs[J]. SPE Reservoir Evaluation & Engineering, 2016, 19(3): 415-428. |
[29] | WAN T, MU Z J. The use of numerical simulation to investigate the enhanced Eagle Ford shale gas condensate well recovery using cyclic CO2 injection method with nano-pore effect[J]. Fuel, 2018, 233: 123-132. |
[30] | ZARRAGOICOECHEA G J, KUZ V A. Van der Waals equation of state for a fluid in a nanopore[J]. Physical Review. E-Statistical, Nonlinear, and Soft Matter Physics, 2002, 65(2 Pt 1): 021110. |
[31] | ZARRAGOICOECHEA G J, KUZ V A. Critical shift of a confined fluid in a nanopore[J]. Fluid Phase Equilibria, 2004, 220(1): 7-9. |
[1] | HE Faqi, LI Junlu, GAO Yilong, WU Jinwei, BAI Xingying, GAO Dun. Development characteristics and potential of fault-fracture reservoir in southwest margin of Ordos Basin [J]. Petroleum Reservoir Evaluation and Development, 2024, 14(5): 667-677. |
[2] | ZHANG Zhichao,BAI Mingxing,DU Siyu. Characteristics of pore dynamics in shale reservoirs by CO2 flooding [J]. Petroleum Reservoir Evaluation and Development, 2024, 14(1): 42-47. |
[3] | WANG Xiaoming,CHEN Junbin,REN Dazhong. Research progress and prospect of pore structure representation and seepage law of continental shale oil reservoir [J]. Reservoir Evaluation and Development, 2023, 13(1): 23-30. |
[4] | ZHU Tong,ZHANG Zhe,FENG Dongjun,ZHENG Rongcai,WANG Feng,PENG Yongmin. Geological characteristics of mud shale in Da'anzhai section of Fulu Town, Liangping [J]. Reservoir Evaluation and Development, 2022, 12(1): 139-149. |
[5] | ZHAO Liqiang,CHEN Yinxin,LIU Pingli,LI Nianyin,LUO Zhifeng,DU Juan. Experimental study on a new type of self-propping fracturing fluid [J]. Reservoir Evaluation and Development, 2020, 10(2): 121-127. |
|