Reservoir Evaluation and Development ›› 2020, Vol. 10 ›› Issue (4): 113-118.doi: 10.13809/j.cnki.cn32-1825/te.2020.04.018
• Conventional Oil and Gas • Previous Articles Next Articles
HOU Jianfeng(),LIU Penggang,CAO Tingyi
Received:
2019-07-19
Online:
2020-08-26
Published:
2020-08-07
CLC Number:
HOU Jianfeng,LIU Penggang,CAO Tingyi. Thermal characteristics and oxidation kinetics study of light crude oil during air injection process[J].Reservoir Evaluation and Development, 2020, 10(4): 113-118.
Table 2
Temperature range and mass loss for different tested samples"
样品 | 低温氧化(LTO) | 燃料沉积(FD) | 高温氧化(HTO) | 燃尽 温度/℃ | |||||
---|---|---|---|---|---|---|---|---|---|
温度/℃ | 峰值温度/℃ | 质量损失/% | 温度/℃ | 质量损失/% | 温度/℃ | 峰值温度/℃ | 质量损失/% | ||
原油-1 | 25~129 | 98 | 5.332 | 129~406 | 61.113 | 406~494 | 453 | 33.562 | 501 |
原油-2 | 25~125 | 74 | 13.401 | 125~409 | 66.061 | 409~516 | 462 | 20.540 | 517 |
原油-3 | 25~122 | 97 | 4.234 | 122~414 | 76.694 | 414~579 | 466 | 19.010 | 594 |
原油-1+储层岩石 | 25~162 | 132 | 4.741 | 162~397 | 33.730 | 397~476 | 433 | 16.512 | 527 |
Table 3
Oxidation kinetic parameters of tested samples"
样品 | 线性拟合斜率 | 活化能/(kJ·mol-1) | 指前因子/min | |||
---|---|---|---|---|---|---|
LTO | HTO | LTO | HTO | LTO | HTO | |
原油-1 | -2 556.352 | -4 595.501 | 48.952 | 87.991 | 67 601 | 575 004 |
原油-2 | -1 447.140 | -4 281.890 | 27.710 | 81.990 | 2.572 | 851.140 |
原油-2 | -1 259.130 | -3 897.054 | 24.114 | 74.623 | 1.480 | 120.235 |
原油-1+储层岩石 | -1 481.016 | -3 061.673 | 28.363 | 58.621 | 42.650 | 776.240 |
[1] | 蒲万芬, 袁成东, 金发扬 , 等. 轻质油藏高压注空气技术应用前景分析[J]. 科技导报, 2013,31(17):72-79. |
PU W F, YUAN C D, JIN F Y , et al. High pressure air injection technique for light oil reservoir: Its development history and application prospect[J]. Science & Technology Review, 2013,31(17):72-79. | |
[2] |
KÖK M V . Characterization of medium and heavy crude oils using thermal analysis techniques[J]. Fuel Processing Technology, 2011,92(5):1026-1031.
doi: 10.1016/j.fuproc.2010.12.027 |
[3] |
KÖK M V . Thermal behavior and kinetics of crude oils at low heating rates by differential scanning calorimeter[J]. Fuel Processing Technology, 2012,96(12):123-127.
doi: 10.1016/j.fuproc.2011.12.027 |
[4] |
GUNDOGAR A S, KÖK M V . Thermal characterization, combustion and kinetics of different origin crude oils[J]. Fuel, 2014,123(2):59-65.
doi: 10.1016/j.fuel.2014.01.058 |
[5] | LIU P G, PU W F, NI J H , et al. Thermal investigation on crude oil oxidation kinetics through TG/DTG and DTA tests[J]. Petroleum Science and Technology, 2016,34(7):685-692. |
[6] | 刘鹏刚, 蒲万芬, 贾虎 , 等. 岩屑存在下油藏注空气原油的氧化热解分析[J]. 燃烧科学与技术, 2015,21(5):464-470. |
LIU P G, PU W F, JIA H , et al. Oil oxidation pyrolysis analysis of oil reservoir air injection in the presence of cutting[J]. Journal of Combustion Science and Technology, 2015,21(5):464-470. | |
[7] | 张永刚, 罗懿, 刘岳龙 , 等. 红河油田轻质原油低温氧化实验及动力学研究[J]. 油气藏评价与开发, 2013,3(6):43-47. |
ZHANG Y G, LUO Y, LIU Y L , et al. LTO experiment and kinetics analysis of light crude in Honghe oilfield[J]. Reservoir Evaluation and Development, 2013,3(6):43-47. | |
[8] |
FAN C, ZAN C, ZHANG Q , et al. The oxidation of heavy oil: thermogravimetric analysis and non-isothermal kinetics using the distributed activation energy model[J]. Fuel Processing Technology, 2014,119(6):146-150.
doi: 10.1016/j.fuproc.2013.10.020 |
[9] |
KÖK M V, ACAR C . Kinetics of crude oil combustion[J]. Journal of Thermal Analysis and Calorimetry, 2006,83(2):445-449.
doi: 10.1007/s10973-005-7152-3 |
[10] |
GREENSFELDER B S, VOGE H H, GOOD G M . Catalytic and thermal cracking of pure hydrocarbons: mechanisms of reaction[J]. Industrial and Engineering Chemistry, 1949,41(11):2573-2584.
doi: 10.1021/ie50479a043 |
[11] |
MOTHÉ M G, CARVALHO C H M, SÉRVULO E F C , et al. Kinetic study of heavy crude oils by thermal analysis[J]. Journal of Thermal Analysis and Calorimetry, 2013,111(11):663-668.
doi: 10.1007/s10973-012-2574-1 |
[12] |
FASSIHI M R, MEYERS K O, BASILE P F . Low-temperature oxidation of viscous crude oils[J]. SPE Reservoir Engineering, 1990,5(4):609-616.
doi: 10.2118/15648-PA |
[13] | PU W F, LIU P G, JIA H , et al. Comparative study of light and heavy oils oxidation using thermal analysis methods[J]. Petroleum Science and Technology, 2015,13(33):1357-1365. |
[14] |
NI J H, JIA H, PU W F , et al. Thermal kinetics study of light oil oxidation using TG/DTG techniques[J]. Journal of Thermal Analysis and Calorimetry, 2014,117(3):1349-1355.
doi: 10.1007/s10973-014-3854-8 |
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